Publications

Department of Chemistry




Publications

Refereed Journal Papers and Book Chapters:

 
45     The first 1-D cyanide-bridged Complex Assembled from a Covalently Tethered [Co(N3O2)Cl(OH2)]22+ Macrocyclic Building Block, R.T. Acha, E.L. Gavey, J. Wang, J.M. Rawson and M. Pilkington, Polyhedron, 2014, in press.
44     An Unusual Single Crystal-to-Single Crystal [2+2] Photocyclization Reaction of a TTF-Aryl-Nitrile Derivative, J.J. Hayward, R. Gumbau-Brisa, C. Clarke, A. Alberola, J.M. Rawson and M. Pilkington, Cryst. Eng. Comm., 2014, DOI:10.1039/C4CE00346B    .
43     Slow Relaxation in the first Penta Aza Dy(III) Macrocyclic Complex, E.L. Gavey, Y. Beldjoudi, J.M. Rawson, T. Stamatatos and M. Pilkington, Chem. Commun., 2014, 50, 374.
42     Supramolecular Chains of High Nuclearity {MnIII25} Barrel-like Single Molecule Magnets, D.P. Giannopolous, A. Thuijs, M. Pilkington, W. Wernsdorfer, G. Christou, T.C. Stamatatos, Chem. Commun., 2014, 50, 779. Front Cover
41     Emissive Molecular Nanomagnets: Introducing Optical Properties in Triangular Oximato MnIII3 SMMs from the Deliberate Replacement of Simple Carboxylate Ligands with their Fluorescent Analogues, D. I. Alexandropoulos,A.M. Mowson,M. Pilkington,V. Bekiari,G. Christou and T. C. Stamatatos, Dalton Trans., 2014, 43. 1965. Front Cover
40     Saddling up Copper − New Twists on a Metallo-wheel, N. Zararabi, J.J. Hayward, W. Clegg and M. Pilkington, Dalton, Trans., 2014, 2352.
39     The use of the triptycene framework for observing O···C=O molecular interactions. A. Lari, E. Bresco, P.M. Pitak. S.J. Coles, P. Belser, A. Beyeler,  M. Pillkington and J.D. Wallis, Cryst. Eng. Comm., 2011, 12, 6978. Hot Article
38     New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene. S. Yang, A. C. Brooks,  L. Martin, P. Day,  M. Pilkington, W. Clegg, R.W. Harrington, L. Russo and J. D. Wallis, Tetrahedron, 2010, 66. 6977.
37     Spin-Spin Interactions in Porphyrin-Based Monoverdazyl Radical Hybrid Spin Systems. P.K. Poddutoori, A. Dion, SJ. Yang, M. Pilkington and J.D. Wallis, Inorg. Chem., 2010, 49, 3516. 
36     Light Induced Hole Transfer in a Hypervalent Phosphorous (V) Octaethylporphyrin Bearing an Axially Linked BEDT-TTF. P. K. Poddutoori, A. Dion, S. Yang, M. Pilkington, J.D. Wallis and A. van der Est, J, Porphyrins and Phthalocyanines, 2010, 14, 178.

35. A Survey of Structure and Catalysis.  Palladium(II), Platinum(II), and Iridium(I) Complexes of 2-Phosphino-1-dimethylaminoferrocenes: C. Metallinos, J. Zaifman, L. Van Belle, L. Dodge and M. Pilkington.  Organometallics, 2009 ,  28,  4534,

34. Rational Approaches to Organic Ferromagnets Based on Neutral Radicals Appended to Organosulfur Donors.  A. Alberola and M. Pilkington, Current Organic Synthesis, 2009 , 6, 66. 

33. Three-Dimensional Bimetallic Octacyanidometalates [MIV{(-CN)4MnII(H2O)2}2. 4H2O]n (M=Nb, Mo, W): Synthesis, Single-Crystal X-ray Diffraction and Magnetism.    M.J. Herrera, P. Franz, R. Podgajny, M. Pilkington, M. Biner, S. Decurtins, H. Stoeckli-Evans,  A. Neels, R. Garde, Y. Dromzee, M. Julve, B. Sieclucka, K. Hashimoto, S. Okhoshi and M. Verdaguer.  Comptes Rendus Chimie,  2008 ,  11,  1192.

32. Towards the Understanding of Magnetic Interactions within a Series of Tetrathiafulvalene-pi-Conjugated-Verdazyl Diradical Cation Systems: A Density Functional Theory Study.   V. Polo, A Alberola, J. Andres, J.  Anthony, and M. Pilkington. Phys. Chem. Chem. Phys., 2008 ,  10,  857.

31.   Synthesis and Characterization of a TTF-pi-Verdazyl Radical - A New Building Block for Conducting and/or Magnetic Systems. M. Chahma, K. Macnamara, A. van der Est, A. Alberola, V. Polo and M. Pilkington , New J. Chem. , 2007 , 31, 1973.

30.    The Preparation of a Highly Reactive 3,3'-Disubstituted-2,2'-Bipyridine Ligand and its Rearrangement to a Novel Quaterpyridine Analogue. J. Wang, H. Stoeckli-Evans, S. Onions, J.K. Halfpenny,  J.D. Wallis and M. Pilkington , J. Chem. Soc., Chem. Commun ., 2007 , 3628. "Front Cover"

29.   A Novel Dinuclear Tridentate Bipyridine Carboxamide Ligand and its Complexation to Copper(II): Synthesis, Structure and Magnetism. J. Wang, B. Djukic   A. Alberola, F.  Razavi and M. Pilkington , Inorg. Chem. , 2007 , 46, 8560.

28.   The Preparation and Coordination Complex of the First Imine Bridged TTF-Pyridine Donor Ligand. M. Chahma, N. Hassan, A. Alberola, H. Stoeckli-Evans and M. Pilkington ,  Inorg. Chem. , 2007, 46, 3807.

27.   The Rational Design of a Covalently Tethered Dinuclear [Mn II (N 3 O 2 )] 2 Macrocyclic Building Block: Synthesis, Structure and Magnetic Properties. J. Wang, B. Slater, A. Alberola, H. Stoeckli-Evans, F. Razavi and M. Pilkington , Inorg. Chem. , 2007 , 46, 4763.-4765

26.   Synthesis and characterization of a new family of spin bearing TTF Ligands, M. Chahma, X-S. Wang, A. van der Est and M. Pilkington , J. Org. Chem ., 2006 , 71 , 2750-2755.

25.   Novel Cyano-Bridged MII9MV6 Molecular Clusters [MII = Mn, Co, Ni; MV = Mo, W]. F. Bonadio, J. Larionova, M. Gross, M. Biner, H. Stoeckli-Evans, S. Decurtins and M. Pilkington , Inorg. Syntheses; Ed. J.R. Shapely, 2004 , Vol. 34 , 156-160.

24.   Clusters and Aggregates with Paramagnetic Centres: Cyano and Oxalato Bridged Systems. M. Pilkington and S. Decurtins, Comprehensive Coordination Chemistry II. Elsevier Science Ltd; Ed. A.K. Powell, 2004 , Vol 6 , Chapter 7. 177-229.

23.   Organosulfur donor with hydroxy groups and its conducting salt: crystal structure and physical properties. S.-X. Liu, A. Neels, H. Stoeckli-Evans, M. Pilkington , J.D. Wallis and S. Decurtins, Polyhedron., 2004 , 23(7) , 1185-1189. 

22.   A rational approach for the self-assembly of molecular building blocks in the field of molecule-based magnetism. M. Pilkington and S. Decurtins, Crystal Engineering in Materials Chemistry. Wiley-VCH, Weinheim, Germany; Ed. G. Desiraju. 2003 , Chapter 7 . 276-322.

21.   The design and synthesis of a novel aza-substituted phthalocyanine with four peripheral diimine binding sites. J. Rusanova, S. Decurtins and M. Pilkington , J. Chem. Soc., Chem. Commun ., 2002 , 19 , 2236-2237.

20.   The facile synthesis of novel functionalized bis(ethylenedithio)tetra-thiafulvalene (BEDT-TTF) derivatives. S.-X. Liu, S. Dolder, M. Pilkington and S. Decurtins, J. Org. Chem ., 2002 , 67(9) , 3160-3162. 

19.   The coordination chemistry of 3,3'-diamino-2,2'-bipyridine and its dication- exploring the role of the amino groups by X-ray crystallography. C.R. Rice, S. Onions, N. Vidal, J.D. Wallis, M.-C. Senna, M. Pilkington and H. Stoeckli-Evans, Eur. J. Inorg. Chem ., 2002 , 8 , 1985-1997. 

18.   New carbon-carbon bond forming reactions of cyclic sulfate esters and cyclic sulfamidates. M.K. Pound, D.L. Davies, M. Pilkington , M.M. de Pina Vaz Sousa and J.D. Wallis, Tet. Lett. , 2002 , 43(10) , 1915-1918.

17.   2,2,2-Tris(cyclohexyloxy)-4,5-(2',2''-biphenylo)-1,3,2-dioxaphospholene. P.G. Jones, A.J. Kirby and M. Pilkington . Acta Cryst ., 2002 , E58(3), 268-269. 

16.   The exploitation of versatile building blocks for the self-assembly of novel molecular magnets. M. Pilkington , M. Gross, P. Franz, M. Biner, S. Decurtins, H. Stoeckli-Evans and A. Neels, J. Solid State Chem ., 2001 , 159(2), 262-267. 

15.   The utilization of classical spin monte carlo methods to stimulate magnetic behaviour of extended three-dimensional cubic networks incorporating M(II) ions with an S = 5/2 ground state spin. E. Boullant, J. Cano, Y. Journaux, S. Decurtins, M. Gross and M. Pilkington , Inorg. Chem., 2001 , 40(16), 3900-3904. 

14.   The design and synthesis of versatile molecular building blocks: working towards the controlled self-assembly of novel functional materials. M. Pilkington and S. Decurtins, Chimia, 2001 , 55(12), 1014-1016. 

13.   Functionalised organosulfur donor molecules: synthesis of racemic hydroxymethyl-, alkoxymethyl- and dialkoxymethylbis(ethylenedithio) tetrathiafulvalenes. N. Saygili, R.J. Brown, P. Day, R. Hoelzl, P. Kathirgamanathan, E.R. Mageean, T. Ozturk, M. Pilkington , M.M.B. Qayyum, S.S. Turner, L. Vorwerg and J.D. Wallis, Tetrahedron , 2001 , 57(23) , 5015-5026. 

12.   Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio)tetrathiafulvalene and related materials. T. Ozturk, N. Saygili, S. Ozkara, M. Pilkington, C.R. Rice, D.A. Tranter, F. Turksy and J.D. Wallis, J. Chem. Soc., Perkin Trans. 1, 2001, (4) , 407-414. 

11.   Molecular distortions in crystalline 2-phenylethynylbenzoic acid. L.D. Hall, G. Orpen, M. Pilkington , J.D. Wallis, J. Chem. Cryst. , 2001 , 32(2), 97-103.

10.   High-Spin molecules. A novel cyano-bridged Mn9IIMo6V molecular cluster with an S = 51/2 ground state and ferromagnetic intercluster ordering at low temperature. J. Larionova, M. Gross, M. Pilkington , H-P. Andres, H. Steockli-Evans, H.-U. Güdel and S. Decurtins. Angew. Chem. Int. Ed , 2000 , 39(9) , 1605-1609. 

9.   Molecular-based magnetism in high-spin molecular clusters and three-dimensional networks based on cyanometalate building blocks. M. Pilkington , S. Decurtins. Chimia , 2000 , 54(10) , 593-601. 

8.   Synthesis and reactivity of tethered n1:n6-(phosphinoarene)ruthenium dichlorides. B. Therrien, T.R. Ward, M. Pilkington , C. Hoffmann, Organometallics, 1998 , 17(3), 330-337. 

7.   4,4'-Dinitro-2,2'-bipyridine. J. Hauser, M. Pilkington , C. Hoffmann, S. Capelli and H.-B. Bürgi., Acta Cryst., 1997 , C53(11) , 1719-1721. 

6.   New precursors for preparing organic conducting materials: synthesis of (R)-(hydroxymethyl)bis(ethylenedithio)tetrathiafulvalene, and the ring expansion of a cyclic sulfate ester. F. Leurquin, T. Ozturk, M. Pilkington and J.D. Wallis, J. Chem. Soc., Perkin Trans. 1, 1997 , (21), 3173-3178.

5.   Geometry distorting intramolecular interactions to an alkyne group in 1-(2-aminophenyl)-2-(2-nitrophenyl)ethyne: a joint experimental- theoretical study. M. Pilkington , J.D. Wallis, G. Smith and J.A.K Howard, J. Chem. Soc., Perkin Trans. 2, 1996 , (9), 1849-1854. 

4.   An alkyne group with a pair of hydrogen bonds: the crystal structure of 2,2'-ethynylenedibenzeneboronic acid at 122 K. M. Pilkington , J.D. Wallis and S. Larsen, J. Chem. Soc., Chem. Commun., 1995 , (15), 1499-1500. 

3.  Attractive interactions between an alkyne group and two carbonyl oxygen atoms: the crystal and molecular structure of 2,2'-ethynylenedibenzoic acid at 150 K. M. Pilkington , S. Tayip, J.D. Wallis, J. Chem. Soc. Perkin. Trans 2 ., 1994 , (12), 2481-2484. 

2.   Methyl DL-3-benzyl-2,2-dioxo-1,2,3-oxathiazolidine-4-carboxylate - an interm- ediate for amino acid synthesis. P. Gritsonie, M. Pilkington and J.D. Wallis. Acta Cryst. , 1994 , C50(5) , 763-765. 

1.   Synthesis and stability of the cyclic sulfamidate of N-trityl-L-serine methyl ester. M. Pilkington and J.D. Wallis, J. Chem. Soc., Chem. Commun ., 1993 , (24), 1857-1858.

POSTAL ADDRESS
Dept. of Chemistry
Brock University
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