FIREWORK COLOURS

The first fireworks were as early as 100 B.C. by the Chinese. The original function of fireworks were for religious ceremonies, but later became used as “flaming arrows” by a variety of military groups.

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image courtesy of Jay Jacobson: http://www.fractalism.com/


Fireworks consist of two different chemical components, gunpowder and “stars”. The gunpowder is composed of Sulphur, charcoal and Potassium nitrate. The chemical composition of the stars will determine what colour you will see when the firework explodes. Different types of chemicals will emit different colours of light when they explode, the chart below shows the chemical composition of different colours of fireworks.

Colour

Chemical Compounds

Red

Strontium salts, lithium salts
lithium carbonate, Li2CO3 = red
strontium carbonate, SrCO3 = bright red

Orange

Calcium salts
calcium chloride, CaCl2
calcium sulphate, CaSO4xH2O, where x = 0,2,3,5

Gold

Incandescence of iron (with carbon), charcoal, or lampblack

Yellow

Sodium compounds
sodium nitrate, NaNO3
cryolite, Na3AlF6

Electric White

White-hot metal, such as magnesium or aluminium
barium oxide, BaO

Green

Barium compounds + chlorine producer
barium chloride, BaCl = bright green

Blue

Copper compounds + chlorine producer
copper acetoarsenite (Paris Green), Cu3As2O3Cu(C2H3O2)2 = blue
copper (I) chloride, CuCl = turquoise blue

Purple

Mixture of strontium (red) and copper (blue) compounds

Silver

Burning aluminium, titanium, or magnesium powder or flakes

 

A typical red firework would contain:

Stars composition (by weight):

Potassium perchlorate (KClO4) – 67%
Strontium carbonate (SrCO3) – 13.5%
Pine root pitch (fuel) – 13.5%
Rice starch (binder) – 6%

Gunpowder composition (by weight):

Potassium nitrate (KNO3) – 75%
Charcoal (Carbon) – 15%
Sulphur – 10%

Question #1

A firework technician wants to make a red firework with a total “star” weight of 247g, and a total gunpowder weight of 126g. How much of each of the 7 chemicals does the technician need?

 

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