SPHENE/TITANITE

General Formula:
CaTiOSiO4
Sample: 88-18 System:
Monoclinic
Sphene
Note the high relief of the sphene grain compared to the other minerals in the field of view.
Field of view = 2.7 mm, plane light
Sphene
Note the high interference colour, of the sphene, which may be masked by the colour of the grain.
Field of view 2.7 mm, crossed polars
Block diagram showing the relationship between the crystallographic axes and the indicatrix axes.

Optical Properties

Colour
Pleochroism
shades of brown, less commonly colourless or yellow
non to weakly pleochroic
Form euhedral to subhedral grains with a wedge or diamond shaped cross section
Relief
RI
very high positive
nalpha = 1.843-1.950
nbeta = 1.870-2.034
ngamma = 1.943-2.110
Cleavage good prismatic cleavage {110}, but not usually obvious in thin section
Birefringence
Interference Colours
0.100-0.192
extreme birefringince produces upper order white/cream interference colours
Twinning simple twins on {100} and lamellar twins on {221}
Interference Figure
Optic Sign
2V
biaxial
positive
2VZ = 17-40°
Optic Orientation X ^ a =-6 to -21 °
Y = b
Z ^ c = +35 to 51°
optic plane = (010)
Composition Al3+ and Fe3+ may substitute for Ti4+, a wide variety of other cations, e.g. REE, U and Th, may substitute for Ti.
Alteration alters to leucoxene
Occurrence a common accessory in a wide variety of igneous and metamorphic rocks. Distinguishing Features very high relief and extreme birefringence


Back to: